発表論文・著書など


［原著論文］

2025

Platinum-Catalyzed Alkenylation of Alcetals with Alkenylsilanes

T. Hattori, J. Matsuda-Komuro, Y. Sakurazawa, N. Chijiwa, D. Fukuda, H. Kinoshita, K. Miura, Org. Lett. 2025, 27, in press.


2024

Platinum-Catalyzed Hydrative Dimerization of Alkynylsilanes to α,β-Unsaturated Ketones

K. Kikuchi-Igarashi, Y. Tahara, H. Hirano, C. Ambe, H. Kinoshita, K. Miura, Org. Lett. 2024, 26, 5689-5694.


Synthesis of Dihydrobenzosiloles and Silacyclopentanes by Double Hydroalumination of Terminal Alkynes

R. Osawa, K. Ogihara, F. Hamasaki, H. Kinoshita, K. Miura, Synlett 2024, 36, 284-288.


Synthetic Route to Benzostannoles via Al-Li-dimetal Intermediate and Their Application to Dibenzofulvene Synthesis

R. Kurokawa, H. Kinoshita, K. Miura, Adv. Synth. Catal. 2024, 366, 1523-1530.


2023

Palladium-Catalyzed Synthesis of 3,6-Diaryl-1-silylfulvenes: A Promising Entry for Preparing 1,3,6-Triarylfulvenes Bearing Three Different Aryl Groups

H. Ohki, H. Kinoshita, K. Miura, Org. Lett. 2023, 25, 1331-1335.


2022

One-Pot Direct Synthesis of Siloles from 1-Bromo-2-silylethynylbenzenes or 1-Bromo-4-silyl-1,3-enynes

K. Kazama, R. Kurokawa, K. Inoue, H. Kinoshita, K. Miura, J. Org. Chem. 2022, 87, 10416-10421.


Regio- and Stereoselective Synthesis of Bromoalkenes by Homolytic Hydrobromination of Alkynes with Hydrogen Bromide

W. Kumaki, H. Kinoshita, K. Miura, Tetrahedron 2022, 110, 132687.


Electrochemical Properties and Electrochromism of 6-Aryl-1,3-bis(trimethylsilyl)fulvenes and Their Derivatives

R. Tatemura, M. Yasutake, H. Kinoshita, K. Miura, J. Org. Chem. 2022, 87, 172-183.


2021

Synthesis of Polysubstituted Germoles and Benzogermoles Using a Substoichiometric Amount of Diisobutylaluminum Hydride

K. Kojima, S. Uchida, H. Kinoshita, K. Miura, Org. Lett. 2021, 23, 4598-4602.


Cyclization of 1-Ethynyl-2-alkenylbenzenes to Naphthalenes Using Et2AlCl and DIBAL-H

Y. Nonoyama, K. Yaguchi, H. Kinoshita, K. Miura, Tetrahedron Lett. 2021, 62, 152682.


2020

1.  Diisobutylaluminum Hydride-Promoted Selectivity-Switchable Synthesis of Benzothiophene Oxides and Benzothiophenes via an Al-Li-dimetallated Intermediate

S. Uchida, H. Kinoshita, K. Miura, Org. Lett. 2020, 22, 3123-3127.


2019

Indium(III)-Catalyzed Intramolecular Addition of Silyl Enolates to Alkynes

H. Kinoshita, K. Negishi, S. Fushimi, K. Miura, Tetrahedron Lett. 2019, 60, 1732-1735.


Palladium-Catalyzed Regio- and Stereoselective Synthesis of (E)-1,3-Bissilyl-6-arylfulvenes from Aryl Iodides and Silylacetylenes

S. Suzuki, H. Kinoshita, K. Miura, Org. Lett. 2019, 21, 1612-1616.


2018

Syntheses of Substituted Benzosiloles and Siloles by Diisobutylaluminium Hydride-promoted Cyclization of 1-Silyl-2-(2-silylethynyl)benzenes and 1,4-Disilylalk-3-en-1-ynes

H. Kinoshita, H. Fukumoto, A. Ueda, K. Miura, Tetrahedron 2018, 74, 1632-1645.


2017

Diisobutylaluminum Hydride-promoted Cyclization of Silylated 1,3-Dien-5-ynes: Application to Total Synthesis of a 20-Norabietane Derivative

H. Kinoshita, K. Yaguchi, T. Tohjima, K. Miura, Tetrahedron Lett. 2017, 58, 1607-1610.


Diisobutylaluminum Hydride-Promoted Cyclization of 1-Hydrosilyl-4-silyl-1,3-enynes to Polysubstituted Siloles

  1. H.Kinoshita, A. Ueda, H. Fukumoto, K. Miura, Org. Lett. 2017, 19, 882-885.

SYNFACTS 2017, 13, 414.


2016

Cyclization of Alk-5-ynyl Ketones Promoted by Tf2NH and In(OTf)3: Selective Synthesis of 5- and 7-Membered Carbocycles

H. Kinoshita, C. Miyama, K. Miura, Tetrahedron Lett. 2016, 57, 5065-5069.


Diisobutylaluminum Hydride-Promoted Cyclization of Benzyl and Phenylsilyl Ethers Bearing a 2-(Trimethylsilyl)ethynyl Group: Syntheses of Indenes and Benzosiloles

H. Kinoshita, H. Fukumoto, T. Tohjima, K. Miura, Tetrahedron Lett. 2016, 57, 3571-3574.


Regioselective Allylation of Carbon Electrophiles with Alkenylsilanes under Dual Catalysis by Cationic Platinum(II) Species

H. Kinoshita, R. Kizu, M. Horikoshi, G. Inoue, M. Fujimoto, M. Saito, J. Ichikawa, A. Hosomi, K. Miura, Synthesis 2016, 48, 520-534.


Diisobutylaluminium Hydride-Promoted Cyclization of o-(Trimethylsilylethynyl)styrenes to Substituted Naphthalenes

H. Kinoshita, K. Yaguchi, T. Tohjima, N. Hirai, K. Miura, Tetrahedron Lett. 2016, 57, 2039-2043.


2015

Platinum-Catalyzed Allylation of Carbon Electrophiles with Alkenylsilanes

H. Kinoshita, R. Kizu, G. Inoue, M. Fujimoto, M. Saito, J. Ichikawa, A. Hosomi, K. Miura, Tetrahedron Lett. 2015, 56, 713-716.


2014

Hydroalumination-Triggered Cyclization of Silylated 1,3-Dien-5-ynes to Polysubstitiuted Benzenes 
H. Kinoshita, T. Tohjima, and K. Miura, Org. Lett. 2014, 16, 4762-4765.


Diisobutylaluminum Hydride-Promoted Cyclization of o-(Trimethylsilylethynyl)-styrenes to Indenes
H. Kinoshita, N. Hirai, and K. Miura, J. Org. Chem. 2014, 79, 8171-8181.


2013

Platinum-Catalyzed One-Pot Alkenylation of Aldehydes Using Alkynes and Triethylsilane: Dual Catalysis by Platinum(II) Chloride

H. Kinoshita, R. Uemura, D. Fukuda, and K. Miura, Org. Lett. 2013, 15, 5538-5541.


Nucleophilic Addition of α-(Dimethylsilyl)nitriles to Aldehydes and Ketones

T. Jinzaki, M. Arakawa, H. Kinoshita, J. Ichikawa, and K. Miura, Org. Lett. 2013, 15, 3750-3753.


Regioselective Synthesis of Multisubstituted Benzenes by Palladium-Catalyzed Intermolecular Reaction of β-Iodo-β-silylstyrenes with Alkynes
H. Kinoshita, H. Takahashi, and K. Miura, Org. Lett. 2013, 15, 2962-2965.


Synthetic Utility of Tribenzyltin Hydride and Its Derivatives as Easily Accessible, Removable, and Decomposable Organotin Reagents

T. Yamakawa, H. Kinoshita, and K. Miura, J. Organomet. Chem. 2013, 724, 129-134.


2011

Dialkylaluminum Hydride-Promoted Cyclodimerization of Silylated 1,3-Enynes via Skeletal Rearrangement

H. Kinoshita, T. Ishikawa, and K. Miura, Org. Lett. 2011, 13 (23), 6192-6195.


2010

Indium(III)-catalyzed Coupling between Alkynes and Aldehydes to α,β-Unsaturated Ketones

K. Miura, K. Yamamoto, A. Yamanobe, K. Ito, H. Kinoshita, J. Ichikawa, and A. Hosomi, Chem. Lett. 2010, 39 (7), 766-767.


2009

Platinum(II)-catalyzed Acetal-ene Reaction: Easy Access to Homoallylic Ethers

K. Miura, H. Izumi, H. Kinoshita, J. Ichikawa, and A. Hosomi, Chem. Lett. 2009, 38 (12), 1204-1205.


Platinum-Catalyzed Nucleophilic Addition of Vinylsilanes at the β-Position

K. Miura, G. Inoue, H. Sasagawa, H. Kinoshita, J. Ichikawa, and A. Hosomi, Org. Lett.2009, 11 (21), 5066-5069.


Efficient Alkenation of Aldehydes and Ketones to α,β-Unsaturated Esters Using α,α-Bis(dimethylsilyl)-substituted Esters

K. Miura, M. Ebine, K. Ootsuka, J. Ichikawa, and A. Hosomi, Chem. Lett. 2009, 38 (8), 832-833.



［総説・本］

2019

木下英典、三浦勝清「水素化ジイソブチルアルミニウムによる分子内炭素―炭素および炭素―ケイ素結合形成反応の開発」

有機合成化学協会誌 2019, 77 (1), 58-68.


2013

三浦勝清「有機ケイ素反応剤を利用する新規炭素―炭素結合形成反応の開発」

ケイ素化学協会誌 2013 (30), 5-12.


2011

三浦勝清「ケイ素-炭素結合の活性化に基づく新規有機合成反応の開発」Organometallic News 2011 (3), 59-64.


三浦勝清、木下英典「ビニルシランと白金触媒を用いる新規有機合成反応の開発」

CACS FORUM (埼玉大学総合研究機構 科学分析支援センター機関誌) 2011, 2, 2-5.


2010

三浦勝清「使える！有機合成反応実践ガイド」丸岡啓二・野崎京子・石井康敬・大寺純蔵・冨岡清 編著，分担執筆，化学同人，2010年，p 36, 37, 48, 49．