学科紹介｜埼玉大学工学部応用化学科


木下　英典
KINOSHITA Hidenori

専門分野	有機材料化学・プロセス工学分野
職位	准教授
学位	博士（工学）

担当科目	応用化学実験II
経歴	１９９６年４月　　京都大学工学部工業化学科入学　２０００年３月　　京都大学工学部工業化学科卒業　２０００年４月　　京都大学大学院工学研究科材料化学専攻修士課程入学　２００２年３月　　京都大学大学院工学研究科材料化学専攻修士課程修了　２００２年４月　　京都大学大学院工学研究科材料化学専攻博士後期課程進学　２００５年３月　　京都大学大学院工学研究科材料化学専攻博士後期課程修了　２００２年４月　　日本学術振興会特別研究員（２００５年３月まで DC１）　２００５年４月　　ファイザー株式会社中央研究所化学研究統括部研究員 (２００７年７月まで）　２００７年７月　　ボストン大学 (Boston University) 博士研究員 John A. Porco, Jr.教授指導 (２００９年３月まで）　２００９年４月　　埼玉大学大学院理工学研究科物質科学部門物質機能領域三浦勝清教授主宰研究室助教　２０１７年８月　　埼玉大学大学院理工学研究科物質科学部門物質機能領域三浦勝清教授主宰研究室准教授　現在に至る
研究紹介	遷移金属触媒や有機金属試薬を用いた新規有機合成反応の開発を行っている。特に、有機金属試薬を利用した多置換ベンゼンの位置選択的合成や縮合環化合物の効率的な合成に取り組んでいる。
研究業績（論文）	Synthesis of Dihydrobenzosiloles and Silacycloalkanes via Double Hydroalumination of Terminal Alkynes Ryusei Osawa, Kotaro Ogihara, Fumine Hamasaki, Hidenori Kinoshita,* and Katsukiyo Miura Synlett 2024, 35, DOI: 10.1055/a-2330-0874. Synthetic Route to Benzostannoles via Al-Li-dimetal Intermediate and Their Application to Dibenzofulvene Synthesis Rei Kurokawa, Hidenori Kinoshita,* and Katsukiyo Miura Advanced Synthesis & Catalysis 2024, 366, 1523-1530. Palladium-Catalyzed Synthesis of 3,6-Diaryl-1-silylfulvenes: A Promising Entry for Preparing 1,3,6-Triarylfulvenes Bearing Three Different Aryl Groups Hayato Ohki, Hidenori Kinoshita,* and Katsukiyo Miura Org. Lett. 2023, 25(8), 1331–1335. One-pot Direct Synthesis of Siloles from 1-Bromo-2-silylethynylbenzenes or 1-Bromo-4-silyl-1,3-enynes Koyo Kazama, Rei Kurokawa, Kei Inoue, Hidenori Kinoshita,* and Katsukiyo Miura J. Org. Chem. 2022, 87(15), 10416–10421. Electrochemical Properties, and Electrochromism of 6-Aryl-1,3-bis(trimethylsilyl)fulvenes and their Derivatives Ryota Tatemura, Mikio Yasutake, Hidenori Kinoshita,* and Katsukiyo Miura J. Org. Chem. 2022(1), 87, 172–183. Synthesis of Polysubstituted Germoles and Benzogermoles Using a Substoichiometric Amount of Diisobutylaluminum Hydride Ko Kojima, Seiya Uchida, Hidenori Kinoshita,* and Katsukiyo Miura Org. Lett. 2021, 23, 4598–4602. Cyclization of 1-ethynyl-2-alkenylbenzenes to naphthalenes using Et2AlCl and DIBAL-H Yuma Nonoyama, Kazuki Yaguchi, Hidenori Kinoshita,* and Katsukiyo Miura Tetrahedron Lett. 2021, 62, 152682. Diisobutylaluminum Hydride Promoted Selectivity-Switchable Synthesis of Benzothiophene Oxides and Benzothiophenes via an Al-Li-dimetallated Intermediate Seiya Uchida, Hidenori Kinoshita,* and Katsukiyo Miura* Org. Lett. 2020, 22(8), 3123-3127. Palladium-Catalyzed Synthesis of 1,3-Bissilyl-6-arylfulvenes via Cyclotrimerization of Trimethylsilylacetylene and Desilylation Souta Suzuki, Hidenori Kinoshita,* and Katsukiyo Miura* Org. Lett. 2019, 21(6), 1612-1616. Development of Intramolecular C-C and C-Si Bond Forming Reactions Promoted by Diisobutylaluminum Hydride Hidenori Kinoshita,* Katsukiyo Miura* Journal of Synthetic Organic Chemistry, Japan 2019 77 (1), 58-68. Syntheses of Substituted Benzosiloles and Siloles by Diisobutylaluminium Hydride-promoted Cyclization of 1-Silyl-2-(2-silylethynyl)benzenes and 1,4-Disilylalk-3-en-1-ynes Hidenori Kinoshita, Hiroki Fukumoto, Akihiro Ueda, and Katsukiyo Miura Tetrahedron 2018, 74(14), 1632-1645. Diisobutylaluminum hydride-promoted cyclization of silylated 1,3-dien-5-ynes: Application to total synthesis of a 20-norabietane derivative Hidenori Kinoshita, Kazuki Yaguchi, Takayuki Tohjima, and Katsukiyo Miura Tetrahedron Lett. 2017, 58, 1607-1610. Diisobutylaluminum Hydride-Promoted Cyclization of 1-Hydrosilyl-4-silyl-1,3-enynes to Polysubstituted Siloles Hidenori Kinoshita, Akihiro Ueda, Hiroki Fukumoto, and Katsukiyo Miura Org. Lett. 2017, 19, 882-885. Diisobutylaluminum hydride-promoted cyclization of benzyl and phenylsilyl ethers bearing a 2-(trimethylsilyl)ethynyl group: syntheses of indenes and benzosiloles Hidenori Kinoshita, Hiroki Fukumoto, Takayuki Tohjima, and Katsukiyo Miura Tetrahedron Lett. 2016, vol. 57, issue 31, 3571-3574. Diisobutylaluminum Hydride-Promoted Cyclization of o-(Trimethylsilylethynyl)styrenes to Substituted Naphthalenes Hidenori Kinoshita, Kazuki Yaguchi, Takayuki Tohjima, Nobuyoshi Hirai, and Katsukiyo Miura Tetrahedron Lett. 2016, 57, 2039-2043. Diisobutylaluminum Hydride-Promoted Cyclization of o-(Trimethylsilylethynyl)-styrenes to Indenes H. Kinoshita, N. Hirai, and K. Miura J. Org. Chem., 2014, 79, 8171-8181. Hydroalumination-Triggered Cyclization of Silylated 1,3-dien-5-ynes to Polysubstitiuted Benzenes H. Kinoshita, T. Tohjima, and K. Miura Org. Lett. 2014, 16, 4762-4765. Platinum-Catalyzed One-Pot Alkenylation of Aldehydes Using Alkynes and Triethylsilane: Dual Catalysis by Platinum(II) Chloride H. Kinoshita, R. Uemura, D. Fukuda, and K. Miura Org. Lett., 2013, 15, 5538–5541. Regioselective Synthesis of Multisubstituted Benzenes by Palladium-Catalyzed Intermolecular Reaction of β-Iodo-β-silylstyrenes with Alkynes Hidenori Kinoshita, Hirotoshi Takahashi, and Katsukiyo Miura Org. Lett., 2013, 15, 2962-2965. Dialkylaluminum Hydride-Promoted Cyclodimerization of Silylated 1,3-Enynes via Skeletal Rearrangement Hidenori Kinoshita, Tomoyuki Ishikawa, and Katsukiyo Miura Org. Lett., 2011, 13, 6192-6195. Tandem Processes Identified from Reaction Screening: Nucleophilic Addition to Aryl N-Phosphinylimines Employing La(III)-TFAA Activation Hidenori Kinoshita, Oscar J. Ingham, Winnie W. Ong, Aaron B. Beeler and John A. Porco, Jr. J. Am. Chem. Soc. 2010, 132, 6412-6418.
所属学会・協会	日本化学会会員　有機合成化学協会会員　近畿化学協会会員　アメリカ化学会会員